GREAT: the SOFIA high-frequency heterodyne instrument

We describe the design and construction of GREAT, the German REceiver for Astronomy at Terahertz frequencies operated on the Stratospheric Observatory for Infrared Astronomy (SOFIA). GREAT is a modular dual-color heterodyne instrument for highresolution far-infrared (FIR) spectroscopy. Selected for SOFIA's Early Science demonstration, the instrument has successfully performed three Short and more than a dozen Basic Science flights since first light was recorded on its April 1, 2011 commissioning flight. We report on the in-flight performance and operation of the receiver that - in various flight configurations, with three different detector channels - observed in several science-defined frequency windows between 1.25 and 2.5 THz. The receiver optics was verified to be diffraction-limited as designed, with nominal efficiencies; receiver sensitivities are state-of-the-art, with excellent system stability. The modular design allows for the continuous integration of latest technologies; we briefly discuss additional channels under development and ongoing improvements for Cycle 1 observations. GREAT is a principal investigator instrument, developed by a consortium of four German research institutes, available to the SOFIA users on a collaborative basis

Distances and classification of amino acids for different protein secondary structures

Window profiles of amino acids in protein sequences are taken as a description of the amino acid environment. The relative entropy or Kullback-Leibler distance derived from profiles is used as a measure of dissimilarity for comparison of amino acids and secondary structure conformations. Distance matrices of amino acid pairs at different conformations are obtained, which display a non-negligible dependence of amino acid similarity on conformations. Based on the conformation specific distances clustering analysis for amino acids is conducted.Comment: 15 pages, 8 figure

[12CII] and [13CII] 158 mum emission from NGC 2024: Large column densities of ionized carbon

Context: We analyze the NGC 2024 HII region and molecular cloud interface using [12CII] and [13CII] observations. Aims: We attempt to gain insight into the physical structure of the interface layer between the molecular cloud and the HII region. Methods. Observations of [12CII] and [13CII] emission at 158 {\mu}m with high spatial and spectral resolution allow us to study the detailed structure of the ionization front and estimate the column densities and temperatures of the ionized carbon layer in the PDR. Results: The [12CII] emission closely follows the distribution of the 8 mum continuum. Across most of the source, the spectral lines have two velocity peaks similar to lines of rare CO isotopes. The [13CII] emission is detected near the edge-on ionization front. It has only a single velocity component, which implies that the [12CII] line shape is caused by self-absorption. An anomalous hyperfine line-intensity ratio observed in [13CII] cannot yet be explained. Conclusions: Our analysis of the two isotopes results in a total column density of N(H)~1.6\times10^23 cm^-2 in the gas emitting the [CII] line. A large fraction of this gas has to be at a temperature of several hundred K. The self-absorption is caused by a cooler (T<=100 K) foreground component containing a column density of N(H)~10^22 cm^-2

A progressive diagonalization scheme for the Rabi Hamiltonian

A diagonalization scheme for the Rabi Hamiltonian, which describes a qubit interacting with a single-mode radiation field via a dipole interaction, is proposed. It is shown that the Rabi Hamiltonian can be solved almost exactly using a progressive scheme that involves a finite set of one variable polynomial equations. The scheme is especially efficient for lower part of the spectrum. Some low-lying energy levels of the model with several sets of parameters are calculated and compared to those provided by the recently proposed generalized rotating-wave approximation and full matrix diagonalization.Comment: 8pages, 1 figure, LaTeX. Accepted for publication in J. Phys. B: At. Mol. Opt. Phy

Development of proton-conducting membranes for hydrogen separation

The objective of this project is to develop dense ceramic membranes that can efficiently and economically separate hydrogen from gaseous mixtures (e.g., syngas, coal gas, etc.). Toward this end, materials with suitable electronic and protonic conductivities will be identified, and methods for fabricating thin, dense ceramic membranes from such materials will be developed. The chemical and mechanical stability of the membranes will be determined to estimate the expected lifetime of the membranes. Scoping-level evaluations will be performed to identify potential applications of proton membrane technology. Areas that will be evaluated include overall market scale, typical site operating scale, process integration opportunities and issues, and alternative-source economics. The literature on mixed electronic/protonic conductors was surveyed to identify suitable candidate materials. SrCe{sub 1{minus}x}M{sub x}O{sub 3{minus}{delta}} and BaCe{sub 1{minus}x}M{sub x}O{sub 3{minus}{delta}} (where M is a fixed-valent dopant such as Ca, Y, Yb, In, Nd, or Gd) were selected for further investigation on the basis of their reported total conductivities and proton transference numbers

Deoxyribonucleic Acid as a Universal Electrolyte for Bio-Friendly Light-Emitting Electrochemical Cells [in press]

In the search for bio and eco‐friendly light sources, light‐emitting electrochemical cells (LECs) are promising candidates for the implementation of biomaterials in their device architecture thanks to their low fabrication complexity and wide range of potential technological applications. In this work, the use of the DNA derivative DNA‐cetyltrimethylammonium (DNA‐CTMA) is introduced as the ion‐solvating component of the solid polymer electrolyte (SPE) in the active layer of solution‐processed LECs. The focus is particularly on the investigation of its electrochemical and ionic conductivity properties demonstrating its suitability for device fabrication and correlation with thin film morphology. Furthermore, upon blending with the commercially available emissive polymer Super Yellow, the structure property relationship between the microstructure and the ionic conductivity is investigated and yields an optimized LEC performance. The large electrochemical stability window of DNA‐CTMA enables a stable device performance for a variety of emitters covering the complete visible spectral range, thus highlighting the universal character of this naturally sourced SPE

Comparative chromosome painting discloses homologous Segments in distantly related mammals

Comparative chromosome painting, termed ZOO-FISH, using DNA libraries from flow sorted human chromosomes 1,16,17 and X, and mouse chromosome 11 discloses the presence of syntenic groups in distantly related mammalian Orders ranging from primates (Homo sapiens), rodents (Mus musculus), even-toed ungulates (Muntiacus muntjak vaginalis and Muntiacus reevesi) and whales (Balaenoptera physalus). These mammalian Orders have evolved separately for 55-80 million years (Myr). We conclude that ZOO-FISH can be used to generate comparative chromosome maps of a large number of mammalian species

Analytical methods in wineries: is it time to change?

A review of the methods for the most common parameters determined in wine—namely, ethanol, sulfur dioxide, reducing sugars, polyphenols, organic acids, total and volatile acidity, iron, soluble solids, pH, and color—reported in the last 10 years is presented here. The definition of the given parameter, official and usual methods in wineries appear at the beginning of each section, followed by the methods reported in the last decade divided into discontinuous and continuous methods, the latter also are grouped in nonchromatographic and chromatographic methods because of the typical characteristics of each subgroup. A critical comparison between continuous and discontinuous methods for the given parameter ends each section. Tables summarizing the features of the methods and a conclusions section may help users to select the most appropriate method and also to know the state-of-the-art of analytical methods in this area

Phylogenetic and molecular analysis of hydrogen-producing green algae

A select set of microalgae are reported to be able to catalyse photobiological H2 production from water. Based on the model organism Chlamydomonas reinhardtii, a method was developed for the screening of naturally occurring H2-producing microalgae. By purging algal cultures with N2 in the dark and subsequent illumination, it is possible to rapidly induce photobiological H2 evolution. Using NMR spectroscopy for metabolic profiling in C. reinhardtii, acetate, formate, and ethanol were found to be key compounds contributing to metabolic variance during the assay. This procedure can be used to test algal species existing as axenic or mixed cultures for their ability to produce H2. Using this system, five algal isolates capable of H2 production were identified in various aquatic systems. A phylogenetic tree was constructed using ribosomal sequence data of green unicellular algae to determine if there were taxonomic patterns of H2 production. H2-producing algal species were seen to be dispersed amongst most clades, indicating an H2-producing capacity preceded evolution of the phylum Chlorophyta